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| The color-change (from bright yellow to orange-gray) in Van Gogh's "Flowers in a blue vase" can be seen to the right and upper right of the painting. Two microsamples were taken from these areas. |
Parts of Vincent van Gogh's "Flowers in a blue vase" painting have
mysteriously changed color over time, and now scientists have figured
out why: A chemical reaction between the paint and a protective varnish
supposedly applied to the painting after the artist's death in 1890
turned his bright yellow flowers an orange-gray color.
The chemical degradation occurred right at the interface between the paint and the varnish, the researchers added.
Van Gogh painted "Flowers in a blue vase" in 1887 in Paris; the
Kröller-Müller Museum in the Netherlands acquired the painting in the
early 20th century. Like many other paintings at the time, this one was
covered with what was considered a protective varnish.
Then, in 2009, a conservation treatment "revealed an unusual gray
opaque crust on parts of the painting with cadmium yellow paint," said
paintings conservator at the museum Margje Leeuwestein in a statement.
The change in color was perplexing and didn't seem to be the result of
simply the coating of varnish aging.
"Varnish can become brown with age
and thus can give all colors a more dark tone," study researcher Koen
Janssens, of the University of Antwerp in Belgium, told LiveScience.
The research team found in an earlier study that photo-oxidation led to a darkening of Van Gogh's bright yellows in two paintings of his, "Bank of the Seine," and "View of Arles with Irises."
"However, when only the varnish has darkened and has not reacted
chemically with the paint below it, it can relatively easily [be]
removed and the original bright colors of the paint will become visible
again," added Janssens, chairman of the university's department of
chemistry.
Mysteriously, he said, the paint beneath the varnish had also become brittle and any attempts to remove the varnish failed — a bit of the gray crust came off with the varnish.
To sleuth out the culprit for the color change without sabotaging a
masterpiece, experts at the museum took two microscopic paint samples
from the original artwork. Janssens and colleagues used powerful, yet
microscopic, X-ray beams to determine the chemical composition as well
as the structure at that paint-varnish interface.
Rather than the
crystalline cadmium sulfate compounds they would expect due to oxidation
of the paint, they found a lead-sulfate compound.
(When ultraviolet and blue light falls on the paint, so-called
photo-oxidation leads to the liberation of cadmium ions and sulfate ions
from the yellow cadmium paint.)
It seems, the researchers said, that the negatively charged sulfate
ions hooked up with lead ions from the varnish to form anglesite, an
opaque lead-sulfate compound. The lead likely came from a lead-based
drying agent, or siccative, added to the varnish.
To keep Van Gogh's painting
from deteriorating further, Janssens suggests two actions. Since the
process starts with the photo-oxidation, he recommends keeping the
masterpiece in lower light conditions. In addition, he suggests using a
more "high-tech type of varnish" that is more stable than the one
previously used.
The Van Gogh analyses, detailed in a forthcoming issue of the journal
Analytical Chemistry, were carried out at the European Synchrotron
Radiation Facility ESRF in Grenoble, France, and the Deutsches
Elektronen-Synchrotron DESY in Hamburg, Germany.
Other mysteries of Van Gogh resolved by science include: a disputed still life is the Real McCoy; his famous sunflowers are genetic mutants; and a painting thought to be a self-portrait actually shows the artist's brother.
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